|
|
3-dehydro-L-gulonate + NADP+ <=> (4R,5S)-4,5,6-trihydroxy-2,3-dioxohexanoate + NADPH + H+
|
1.1.1.130
3-dehydro-L-gulonate 2-dehydrogenase
|
–
|
K
|
|
BRENDA:
BR29197
KEGG:
R02639
MetaCyc:
3-DEHYDRO-L-GULONATE-2-DEHYDROGENASE-RXN
|
|
|
|
3-dehydro-L-gulonate + NAD+ <=> (4R,5S)-4,5,6-trihydroxy-2,3-dioxohexanoate + NADH + H+
|
1.1.1.130
3-dehydro-L-gulonate 2-dehydrogenase
|
–
|
BMK
|
|
BRENDA:
BR29197-a
KEGG:
R02637
MetaCyc:
3-DEHYDRO-L-GULONATE-2-DEHYDROGENASE-RXN_WOP;
RXN0-703
|
|
|
|
dehydroascorbate + H2O <=> (4R,5S)-4,5,6-trihydroxy-2,3-dioxohexanoate
|
0.0.0.0
3.1.1.17
gluconolactonase
|
–
–
|
BMK
|
|
BRENDA:
BR52869
KEGG:
R04785
MetaCyc:
RXN-21400
|
|
|
|
(4R,5S)-4,5,6-trihydroxy-2,3-dioxohexanoate + H2O <=> L-xylonate + CO2
|
4.1.1
|
–
|
K
|
|
KEGG:
R04515
|
|
|
|
(4R,5S)-4,5,6-trihydroxy-2,3-dioxohexanoate + H2O <=> L-lyxonate + CO2
|
4.1.1
|
–
|
K
|
|
KEGG:
R04784
|
|
|
|
dehydroascorbate_(bicyclic_form) <=> (4R,5S)-4,5,6-trihydroxy-2,3-dioxohexanoate + H+
|
not assigned
|
–
|
|
|
MetaCyc:
RXN-12861
|
|
|
|
(4R,5S)-4,5,6-trihydroxy-2,3-dioxohexanoate <=> 2-carboxy-L-lyxonolactone
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-12870
|
|
|
|
Na+ + (4R,5S)-4,5,6-trihydroxy-2,3-dioxohexanoate <=> Na+ + (4R,5S)-4,5,6-trihydroxy-2,3-dioxohexanoate
|
not assigned
|
–
|
|
|
MetaCyc:
TRANS-RXN0-235
|
|
|
|
(4R,5S)-4,5,6-trihydroxy-2,3-dioxohexanoate <=> D-xylonate + CO2
|
4.1.1.34
dehydro-L-gulonate decarboxylase
|
–
|
|
|
BRENDA:
BS1415
|
|
|
|
2-keto-L-gulonate + NADH <=> (4R,5S)-4,5,6-trihydroxy-2,3-dioxohexanoate + NAD+
|
1.1.1.45
L-gulonate 3-dehydrogenase
|
–
|
|
|
BRENDA:
BS188150
|
|
|
|
(4R,5S)-4,5,6-trihydroxy-2,3-dioxohexanoate + NADH + H+ <=> 3-dehydro-L-gulonate + NAD+
|
1.1.1.130
3-dehydro-L-gulonate 2-dehydrogenase
|
–
|
|
|
BRENDA:
BS450922
|
|